Coordination Behavior of the 1,2,3-Triphosphaferrocene [Cp′′′Fe(η5-P3C2(H)Ph)] with Organometallic Moieties

DOI to cite this document:: 10.5283/epub.15096

Deng, Shining ; Schwarzmaier, Christoph ; Zabel, Manfred ; Nixon, John F. ; Timoshkin, Alexey Y. ; Scheer, Manfred

PDF
(292kB) - Repository staff only

Date of publication of this fulltext: 07 Jun 2010 12:17

Alternative links to fulltext:DOI

Details

Export bibliographical data

Abstract

The reaction of the 1,2,3-triphosphaferrocene [Cp′′′Fe(η5-P3C2(H)Ph)] (1) with the Lewis acidic complex [PtCl2(PEt3)]2 yields the monosubstituted derivative [Cp′′′Fe(η5-P3C2(H)Ph){PtCl2(PEt3)}] (2), in which the Pt moiety is located at the P atom adjacent to the C(H) group of the cyclo-P3C2 ring. Using an excess of the Pt complex no multiple substitution occurs. In contrast, using [W(CO)5] units ...