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- DOI to cite this document:
- 10.5283/epub.15096
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Abstract
The reaction of the 1,2,3-triphosphaferrocene [Cp′′′Fe(η5-P3C2(H)Ph)] (1) with the Lewis acidic complex [PtCl2(PEt3)]2 yields the monosubstituted derivative [Cp′′′Fe(η5-P3C2(H)Ph){PtCl2(PEt3)}] (2), in which the Pt moiety is located at the P atom adjacent to the C(H) group of the cyclo-P3C2 ring. Using an excess of the Pt complex no multiple substitution occurs. In contrast, using [W(CO)5] units ...

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