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Neue Pentaphosphaferrocene [New Pentaphosphaferrocenes]

DOI to cite this document:
Dielmann, Fabian ; Merkle, Roger ; Heinl, Sebastian ; Scheer, Manfred
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Date of publication of this fulltext: 07 Jun 2010 12:17


By cothermolysis of [CpRFe(CO)2]2 [CpR = η5-C5(CH2Ph)5 (Cpbn) (1) and η5-C5Me4C2H4SMe (CpS) (2)] with P4 phosphorus two novel pentaphosphaferrocenes of the formula [CpRFe(η5-P5)] [CpR = CpS (3), Cpbn (4)] have been synthesised and comprehensively characterised. These two products represent the first derivatives of this class of compounds with a functionalised as well as a sterically bulky ...


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