Neue Pentaphosphaferrocene [New Pentaphosphaferrocenes]

DOI to cite this document:: 10.5283/epub.15097

Dielmann, Fabian ; Merkle, Roger ; Heinl, Sebastian ; Scheer, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:17

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Item type:	Article
Journal or Publication Title:	Zeitschrift für Naturforschung B
Publisher:	Verlag der Zeitschrift für Naturforschung
Volume:	64
Page Range:	pp. 3-10
Date:	29 January 2009
Institutions:	Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:	Ferrocene, Pentabenzylcyclopentadiene Ligand, Phosphorus, Iron, Pentaphosphaferrocene
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Unknown
Created at the University of Regensburg:	Unknown
Item ID:	15097

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Abstract

By cothermolysis of [CpRFe(CO)2]2 [CpR = η5-C5(CH2Ph)5 (Cpbn) (1) and η5-C5Me4C2H4SMe (CpS) (2)] with P4 phosphorus two novel pentaphosphaferrocenes of the formula [CpRFe(η5-P5)] [CpR = CpS (3), Cpbn (4)] have been synthesised and comprehensively characterised. These two products represent the first derivatives of this class of compounds with a functionalised as well as a sterically bulky ...

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