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Unexpected Differences in the Coordination Behaviour of 1,2,4-Triphosphaferrocenes towards Cu Chloride

Deng, Shining, Schwarzmaier, Christoph, Vogel, Ulf, Zabel, Manfred, Nixon, John F. and Scheer, Manfred (2009) Unexpected Differences in the Coordination Behaviour of 1,2,4-Triphosphaferrocenes towards Cu Chloride. European Journal of Inorganic Chemistry 2008 (31), pp. 4870-4874.

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Abstract

The coordination behaviour of 1,2,4-triphosphaferrocenes [FeCpR(5-P3C2tBu2)] [CpR = Cp (1), Cp (2)] towards CuI chloride is significantly influenced by the substitution pattern of the cyclopentadienyl ring attached to iron. The dimeric copper complexes [{FeCp(5:1:1-P3tBu2C2)}{-CuCl(MeCN)}]2 (3) and [{FeCp (5:1:1-P3tBu2C2)}(-CuCl)]2 (4), in which two 1,2,4-triphosphaferrocenes are linked by two ...

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Item type:Article
Date:25 September 2009
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.200800852DOI
Keywords:Supramolecular chemistry; Copper; Fragmentation reactions; Tri­phosphaferrocenes; Tetraphosphabutadiene ligand
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:15101
Owner only: item control page

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