Unexpected Differences in the Coordination Behaviour of 1,2,4-Triphosphaferrocenes towards Cu Chloride

DOI to cite this document:: 10.5283/epub.15101

Deng, Shining ; Schwarzmaier, Christoph ; Vogel, Ulf ; Zabel, Manfred ; Nixon, John F. ; Scheer, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:19

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Abstract

The coordination behaviour of 1,2,4-triphosphaferrocenes [FeCpR(eta(5)-P(3)C(2)tBu(2))] [Cp-R = Cp (1), Cp''' (2)] towards Cu-I chloride is significantly influenced by the substitution pattern of the cyclopentadienyl ring attached to iron. The dimeric copper complexes [{FeCP(eta(5):eta(1):eta(1)-p(3)tBu(2)C(2))} {mu-CuCl-(MeCN)}(2) (3) and [{FeCp''' ...