Go to content
UR Home

Selective halogenation at the pnictogen atom in Lewis-acid/base-stabilised phosphanylboranes and arsanylboranes

DOI to cite this document:
Schwan, Karl-Christian ; Adolf, Ariane ; Vogel, Ulf ; Thoms, Christine ; Zabel, Manfred ; Timoshkin, Alexey Y. ; Scheer, Manfred
(172kB) - Repository staff only
Date of publication of this fulltext: 07 Jun 2010 12:20


The halogenation of Lewis-acid/base-stabilised phosphanylboranes ( 1a) and arsanylboranes ( 1b) with CX4 (X = Cl, Br) leads selectively to the substitution of both protons at the pentel atom and the new compounds [(CO)5W(X2PBH2·NMe3)] ( 2a: X = Cl, 2b: X = Br) and [(CO)5W(X2AsBH2·NMe3)] ( 3a: X = Cl, 3b: X = Br), respectively, are obtained. The new products were comprehensively characterised by ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons