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Reactivity of Transition Metal-Phosphorus Triple Bonds towards Triply Bonded [{CpMo(CO)2}2]: Formation of Heteronuclear Cluster Compounds

Scheer, Manfred ; Himmel, Daniel ; Kuntz, Christian ; Zhan, Shuzhong ; Leiner, Eva
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Date of publication of this fulltext: 07 Jun 2010 12:21


Abstract

Thermolysis of [Cp*P{W(CO)5}2] (1) in the presence of [{CpMo(CO)2}2] leads to the novel complexes [{(CO)2Cp*W}{CpMo(CO)2}(,2:1:1-P2{W(CO)5}2)] (6; Cp=5-C5H5, Cp*=5-C5Me5), [{(-O)(CpMoWCp*)W(CO)4}{3-PW(CO)5}2] (7), [{CpMo(CO)2}2{Cp*W(CO)2}{3-PW(CO)5}] (8) and [{CpMo(CO)2}2{Cp*W(CO)2}(3-P)] (9). The structural framework of the main products 8 and 9 can be described as a tetrahedral Mo2WP unit that ...

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