Reactivity of Transition Metal-Phosphorus Triple Bonds towards Triply Bonded [{CpMo(CO)2}2]: Formation of Heteronuclear Cluster Compounds

DOI to cite this document:: 10.5283/epub.15103

Scheer, Manfred

; Himmel, Daniel ; Kuntz, Christian ; Zhan, Shuzhong ; Leiner, Eva

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Date of publication of this fulltext: 07 Jun 2010 12:21

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Abstract

Thermolysis of [Cp*P{W(CO)(5)}(2)] (1) in the presence Of [{CpMo(CO)(2)}(2)] leads to the novel complexes [{(CO)(2)CP*W}-(CpMo(CO)(2)} (mu,eta(2):eta(1):eta(1)-P-2[W(CO)(5)}(2))] (6; Cp = eta(5)-C5H5, Cp* = eta(5)-C5Me5), [{(mu-O)(CpMoWCp*)W(CO)(4)}{mu(3)-PW(CO)(5))(2)] (7), [{CpMo(CO)(2)}(2)-{Cp*W(CO)(2)}{mu(3)-PW(CO)(5)}] (8) and [{CpMo(CO)(2)}(2){Cp*W(CO)(2)}(mu(3)-P)] (9). The structural ...