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Dimolybdenum Bis-2,4,6-triisopropyl-benzoate Bis-4-isonicotinate: A Redox Active Analogue of 4,4′-Bipyridine with Ambivalent Properties

Chisholm, Malcolm H., Dann, Angela S., Dielmann, Fabian, Gallucci, Judith C., Wolmershäuser, Gotthelf, Patmore, Nathan J., Ramnauth, Ramkrishna and Scheer, Manfred (2008) Dimolybdenum Bis-2,4,6-triisopropyl-benzoate Bis-4-isonicotinate: A Redox Active Analogue of 4,4′-Bipyridine with Ambivalent Properties. Inorganic Chemistry 47 (20), pp. 9248-9255.

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Abstract

The reaction between Mo2(TiPB)4 and 4-iso-nicotinic acid (2 equiv) in ethanol leads to the formation of trans-Mo2(TiPB)2(nic)2, I, where TiPB = 2,4,6-triisopropylbenzoate and nic = 4-isonicotinate. The molecular structures of I and I·2DMSO were determined in the solid state by a single-crystal X-ray study, and its electronic structure was determined by DFT calculations on a model compound, where ...

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Item type:Article
Date:26 September 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1021/ic800693rDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:15105
Owner only: item control page

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