Dimolybdenum Bis-2,4,6-triisopropyl-benzoate Bis-4-isonicotinate: A Redox Active Analogue of 4,4′-Bipyridine with Ambivalent Properties

DOI to cite this document:: 10.5283/epub.15105

Chisholm, Malcolm H. ; Dann, Angela S. ; Dielmann, Fabian ; Gallucci, Judith C. ; Wolmershäuser, Gotthelf

; Patmore, Nathan J. ; Ramnauth, Ramkrishna

; Scheer, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:22

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Abstract

The reaction between Mo-2(TiPB)(4) and 4-iso-nicotinic acid (2 equiv) in ethanol leads to the formation of trans-Mo-2(TiPB)(2)(nic)(2), 1, where TiPB = 2,4,6-triisopropylbenzoate and nic = 4-isonicotinate. The molecular structures of I and I-2DMSO were determined in the solid state by a single-crystal X-ray study, and its electronic structure was determined by DFT calculations on a model ...