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Temperature Controlled Reversible Change of the Coordination Modes of the Highly Symmetrical Multitopic Ligand To Construct Coordination Assemblies: Experimental and Theoretical Studies

Zheng, Bo, Dong, Hao, Bai, Junfeng, Li, Yizhi, Li, Shuhua and Scheer, Manfred (2008) Temperature Controlled Reversible Change of the Coordination Modes of the Highly Symmetrical Multitopic Ligand To Construct Coordination Assemblies: Experimental and Theoretical Studies. Journal of the American Chemical Society 132 (25), pp. 7778-7779.

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Date of publication of this fulltext: 07 Jun 2010 12:23

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Abstract

By fine-tuning the reaction temperature to 5, 15, 30, and 50 °C, respectively, four different complexes, [Cd(HC4O4)2(H2O)4] (1), [Cd4(C4O4)4(H2O)16]•(H2O)2 (2), [Cd(C4O4)(H2O)2] (3), and [Cd(C4O4)(H2O)2] (4), were formed successfully from the identical initial reaction mixture. Moreover, an unprecedented reversible interconversion among the four complexes at the corresponding reaction temperatures mediated by the mother liquor was observed.


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Item type:Article
Date:30 May 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1021/ja800439pDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:15106
Owner only: item control page

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