Go to content
UR Home

Temperature Controlled Reversible Change of the Coordination Modes of the Highly Symmetrical Multitopic Ligand To Construct Coordination Assemblies: Experimental and Theoretical Studies

DOI to cite this document:
Zheng, Bo ; Dong, Hao ; Bai, Junfeng ; Li, Yizhi ; Li, Shuhua ; Scheer, Manfred
(157kB) - Repository staff only
Date of publication of this fulltext: 07 Jun 2010 12:23


By fine-tuning the reaction temperature to 5, 15, 30, and 50 °C, respectively, four different complexes, [Cd(HC4O4)2(H2O)4] (1), [Cd4(C4O4)4(H2O)16]•(H2O)2 (2), [Cd(C4O4)(H2O)2] (3), and [Cd(C4O4)(H2O)2] (4), were formed successfully from the identical initial reaction mixture. Moreover, an unprecedented reversible interconversion among the four complexes at the corresponding reaction temperatures mediated by the mother liquor was observed.

Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: daten@ur.de
0941 943 -5707

Contact persons