Synthesis and Crystal Structures of Novel Copper(I) Complexes of a Phosphanylborane

DOI to cite this document:: 10.5283/epub.15111

Schwan, Karl-Christian ; Adolf, Ariane ; Bodensteiner, Michael ; Zabel, Manfred ; Scheer, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:27

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Abstract

The novel copper iodide clusters [Cu3(-I)(3-I)2(PH2BH2·NMe3)3] (2) and [Cu4(-I)2(3-I)2(PH2BH2·NMe3)3] (3) were synthesized by treating CuI with the primary phosphine (H2PBH2·NMe3). The novel features of both compounds, which have been characterized by X-ray crystallography, are the unsymmetrical constitution of the copper iodide core due to the influence of the monodentate phosphorus ligand. This ...