Synthesis and Crystal Structures of Novel Copper(I) Complexes of a Phosphanylborane

DOI to cite this document:: 10.5283/epub.15111

Schwan, Karl-Christian ; Adolf, Ariane ; Bodensteiner, Michael ; Zabel, Manfred ; Scheer, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:27

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Abstract

The novel copper iodide clusters [Cu-3(mu-I)(mu(3)-I)(2)(PH2BH2 center dot NMe3)(3)] (2) and [Cu-4(mu-I)(2)(mu(3)-I)(2)(PH2BH2 center dot NMe3)(3)] (3) were synthesized by treating CuI with the primary phosphine (H2PBH2 center dot NMe3). The novel features of both compounds, which have been characterized by X-ray crystallography, are the unsymmetrical constitution of the copper iodide core due to ...