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Synthesis and Crystal Structures of Novel Copper(I) Complexes of a Phosphanylborane

Schwan, Karl-Christian, Adolf, Ariane, Bodensteiner, Michael, Zabel, Manfred and Scheer, Manfred (2008) Synthesis and Crystal Structures of Novel Copper(I) Complexes of a Phosphanylborane. Zeitschrift für anorganische und allgemeine Chemie 634 (8), pp. 1383-1387.

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The novel copper iodide clusters [Cu3(-I)(3-I)2(PH2BH2·NMe3)3] (2) and [Cu4(-I)2(3-I)2(PH2BH2·NMe3)3] (3) were synthesized by treating CuI with the primary phosphine (H2PBH2·NMe3). The novel features of both compounds, which have been characterized by X-ray crystallography, are the unsymmetrical constitution of the copper iodide core due to the influence of the monodentate phosphorus ligand. This ...


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Item type:Article
Date:26 May 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Boron; Phosphorus; Copper; Iodide; Cluster compounds
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15111
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