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Self-Assemblies Based on [Cp2Mo2(CO)4(,2-P2)] - Solid-State Structure and Dynamic Behaviour in Solution

Scheer, Manfred, Gregoriades, Laurence John, Zabel, Manfred, Bai, Junfeng, Krossing, Kai, Brunklaus, Gunther and Eckert, Hellmut (2008) Self-Assemblies Based on [Cp2Mo2(CO)4(,2-P2)] - Solid-State Structure and Dynamic Behaviour in Solution. Chemistry - A European Journal 14 (1), pp. 282-295.

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Reaction of complex [Cp2Mo2(CO)4(,2-P2)] (Cp=C5H5 (1)) with CuPF6, AgX (X=BF4, ClO4, PF6, SbF6, Al{OC(CF3)3}4) and [(Ph3P)Au(THF)][PF6] (THF=tetrahydrofuran), respectively, results in the facile formation of the dimers 3 b-h of the general formula [M2({Cp2Mo2 (CO)4(,2:2-P2)}2)({Cp2Mo2(CO)4 (,2:1:1-P2)}2)][X]2 (M=Cu, Ag, Au; X=BF4, ClO4, PF6, SbF6, Al{OC(CF3)3}4). As revealed by X-ray ...


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Item type:Article
Date:26 September 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:density functional calculations; group 11 metals; molybdenum; NMR spectroscopy; phosphorus
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15128
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