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Self-Assemblies Based on [Cp2Mo2(CO)4(,2-P2)] - Solid-State Structure and Dynamic Behaviour in Solution

DOI to cite this document:
10.5283/epub.15128
Scheer, Manfred ; Gregoriades, Laurence John ; Zabel, Manfred ; Bai, Junfeng ; Krossing, Kai ; Brunklaus, Gunther ; Eckert, Hellmut
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Date of publication of this fulltext: 07 Jun 2010 12:31


Abstract

Reaction of complex [Cp2Mo2(CO)4(,2-P2)] (Cp=C5H5 (1)) with CuPF6, AgX (X=BF4, ClO4, PF6, SbF6, Al{OC(CF3)3}4) and [(Ph3P)Au(THF)][PF6] (THF=tetrahydrofuran), respectively, results in the facile formation of the dimers 3 b-h of the general formula [M2({Cp2Mo2 (CO)4(,2:2-P2)}2)({Cp2Mo2(CO)4 (,2:1:1-P2)}2)][X]2 (M=Cu, Ag, Au; X=BF4, ClO4, PF6, SbF6, Al{OC(CF3)3}4). As revealed by X-ray ...

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