Unusual Coordination Behaviour of Pn-Ligand Complexes with Tl+ [Ungewöhnliches Koordinationsverhalten von Pn-Ligandkomplexen gegenüber Tl+]

DOI to cite this document:: 10.5283/epub.15132

Welsch, Stefan ; Gregoriades, Laurence John ; Sierka, Marek ; Zabel, Manfred ; Virovets, Alexander ; Scheer, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:32

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Abstract

Pentaphosphaferrocene coordinates as a ligand to the large monocation Tl+. In addition, one of the phosphorus atoms of each cyclo-P5 moiety coordinates to a neighboring Tl+ ion to give a one-dimensional polymer. Even at low temperatures, fast rotation of the P5 rings is observed in solution and in the solid state.

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