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Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule

Scheer, Manfred ; Schinder, Andrea ; Merkle, Roger ; Johnson, Brian P. ; Linseis, Michael ; Winter, Rainer F. ; Anson, Christopher E. ; Virovets, Alexander
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Date of publication of this fulltext: 07 Jun 2010 12:34


Abstract

C60[Cu26Cl26L2{Cp*Fe(η5-P5)}13(CH3CN)9] (L = H2O) represents a first example of a complete encapsulation of C60 itself by an inorganic fullerene-like system via molecular recognition of the five- and sixfold-symmetric structural motif of C60. The product exhibits an inorganic cover consisting of 99 inorganic core atoms from pentaphosphaferrocene and Cu(I) chloride building blocks. This is the ...

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