Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule

DOI to cite this document:: 10.5283/epub.15134

Scheer, Manfred

; Schinder, Andrea ; Merkle, Roger ; Johnson, Brian P.

; Linseis, Michael

; Winter, Rainer F. ; Anson, Christopher E.

; Virovets, Alexander

PDF
(109kB) - Repository staff only

Date of publication of this fulltext: 07 Jun 2010 12:34

Alternative links to fulltext:DOI

Details

Indexed in

Export bibliographical data

Abstract

C-60 subset of[Cu26Cl26L2{Cp*Fe(P-eta 5-(5))}(13)(CH3CN)(9)] (L = H2O) represents a first example of a complete encapsulation of C-60 itself by an inorganic fullerene-like system via molecular recognition of the five- and sixfold-symmetric structural motif of C-60. The product exhibits an inorganic cover consisting of 99 inorganic core atoms from pentaphosphaferrocene and Cu(I) chloride building ...