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An Unusual Building Block for Supramolecular Aggregates: The Mixed Group 15/16 Element Ligand Complex [(Cp*Mo)2(,3-P3)(,2-PS)] [Ein ungewöhnlicher Baustein für supramolekulare Aggregate aus Elementen der Gruppe 15 und 16: der gemischte Ligandkomplex [(Cp*Mo)2(,3-P3)(,2-PS)]]

Gregoriades, Laurence John, Balázs, Gábor, Brunner, Eike, Gröger, Christian, Wachter, Joachim, Zabel, Manfred and Scheer, Manfred (2007) An Unusual Building Block for Supramolecular Aggregates: The Mixed Group 15/16 Element Ligand Complex [(Cp*Mo)2(,3-P3)(,2-PS)] [Ein ungewöhnlicher Baustein für supramolekulare Aggregate aus Elementen der Gruppe 15 und 16: der gemischte Ligandkomplex [(Cp*Mo)2(,3-P3)(,2-PS)]]. Angewandte Chemie International Edition 46 (31), pp. 5966-5970.

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Abstract

Unusual suspect: The complex [(Cp*Mo)2(,3-P3)(,2-PS)] reacts with CuI and Ag[Al{OC(CF3)3}4] to form two novel linear polymers (see structure of CuI derivative; Cu light blue, I violet, Mo blue, P pink, S yellow). Even with X-ray crystallographic data available, the fact that the sulfur atoms in these polymers do not coordinate to the Group 11 metal centers could only be established with the help of 31P MAS NMR spectroscopy. Cp*=C5Me5


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Item type:Article
Date:2 July 2007
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.200701343DOI
Keywords:Group 11 metals; molybdenum; phosphorus; sulfur; supramolecular chemistry
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:15138
Owner only: item control page

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