Pushkarevsky, Nikolay A. 
; Konchenko, Sergey N. ; Scheer, Manfred
Alternative Links zum Volltext:DOI
| Dokumentenart: | Artikel |
|---|
| Titel eines Journals oder einer Zeitschrift: | Journal of Cluster Science |
|---|
| Verlag: | SPRINGER/PLENUM PUBLISHERS |
|---|
| Ort der Veröffentlichung: | NEW YORK |
|---|
| Band: | 18 |
|---|
| Nummer des Zeitschriftenheftes oder des Kapitels: | 3 |
|---|
| Seitenbereich: | S. 606-617 |
|---|
| Datum: | September 2007 |
|---|
| Institutionen: | Chemie und Pharmazie > Institut für Anorganische Chemie |
|---|
| Identifikationsnummer: | | Wert | Typ |
|---|
| 10.1007/s10876-007-0148-3 | DOI |
|
|---|
| Stichwörter / Keywords: | HETEROMETALLIC CARBONYL CLUSTERS; PLATINUM; LIGANDS; ANIONS; REACTIVITY; COMPLEXES; CHEMISTRY; SULFIDE; BONDS; cluster; carbonyl complexes; iron; platinum; selenium; tellurium |
|---|
| Dewey-Dezimal-Klassifikation: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
|---|
| Status: | Veröffentlicht |
|---|
| Begutachtet: | Unbekannt / Keine Angabe |
|---|
| An der Universität Regensburg entstanden: | Unbekannt / Keine Angabe |
|---|
| Dokumenten-ID: | 15140 |
|---|
Zusammenfassung
The reaction of K-2[Fe-3(mu(3)-Q)(CO)(9)] (Q = Se (K-2[1a]), Te (K-2[1b])) with [(dppm)PtCl2] leads to the addition of a [(dppm)Pt](2+) unit to a Fe(2)Q face of the initial cluster. By this way new heteronuclear clusters [Fe3Pt(mu(3)-Q)(CO)(9)(dppm)] were obtained possessing a butterfly-shaped cluster core bridged by a mu(4)-Q unit. It has been found that the resulting Fe-Pt clusters exist as ...
Zusammenfassung
The reaction of K-2[Fe-3(mu(3)-Q)(CO)(9)] (Q = Se (K-2[1a]), Te (K-2[1b])) with [(dppm)PtCl2] leads to the addition of a [(dppm)Pt](2+) unit to a Fe(2)Q face of the initial cluster. By this way new heteronuclear clusters [Fe3Pt(mu(3)-Q)(CO)(9)(dppm)] were obtained possessing a butterfly-shaped cluster core bridged by a mu(4)-Q unit. It has been found that the resulting Fe-Pt clusters exist as equilibrium mixtures of two isomeric forms in solution differing by the dppm coordination mode: as a chelate ligand coordinated to Pt or as a bridging ligand coordinated to Pt and Fe atoms. The mixtures of isomers can be separated by chromatography and the pure isomers can be isolated as stable crystalline phases. Solutions of both isomers attain equilibrium at normal conditions in about 1 month as found by NMR.
Altmetric