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Conformational Analysis of One-Dimensional Coordination Polymers Based on [Cp2Cr2(CO)4(,2-P2)] by Solid-State Multinuclear NMR Spectroscopy and Density Functional Calculations

Scheer, Manfred, Gregoriades, Laurence John, Zabel, Manfred, Sierka, Marek, Zhang, Long and Eckert, Hellmut (2007) Conformational Analysis of One-Dimensional Coordination Polymers Based on [Cp2Cr2(CO)4(,2-P2)] by Solid-State Multinuclear NMR Spectroscopy and Density Functional Calculations. European Journal of Inorganic Chemistry 2007 (18), pp. 2775-2782.

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Abstract

Reaction of the complex [Cp2Cr2(CO)4(,2-P2)] (2) with copper(I) halides leads to the quantitative formation of the new one-dimensional (1D) linear polymers [CuX{Cp2Cr2(CO)4(,2:1:1-P2)}]n [X = Cl (3), Br (4), I (5)]. Polymers 3-5 are the first examples of supramolecular aggregates incorporating 2 as a connecting moiety. The solid-state structures of 3-5 are compared and their remarkable ...

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Item type:Article
Date:8 May 2007
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.200700092DOI
Keywords:Chromium; Copper; Halides; Density functional calculations; NMR spectroscopy; Phosphorus
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:15141
Owner only: item control page

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