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Main Group Lewis Acid/Base-Stabilised Phosphanylboranes

Adolf, Ariane, Zabel, Manfred and Scheer, Manfred (2007) Main Group Lewis Acid/Base-Stabilised Phosphanylboranes. European Journal of Inorganic Chemistry 2007 (15), pp. 2136-2143.

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The parent compounds of phosphanylboranes of the type (LA)H2P-BH2(LB) (LA = Lewis acid, LB = Lewis base) stabilised by Lewis acid/Lewis base have been synthesised by using perfluorinated main-group Lewis acids. The Lewis acid-phosphane adducts (C6F5)3BPH3, (C6F5)3BPPhH2 and (C6F5)3GaPPhH2 (3) were used as starting materials, which upon lithiation with nBuLi react with the chlorinated Lewis base ...


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Item type:Article
Date:10 April 2007
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Boron; Phosphorus; Hydrides; Lewis acids; Lewis bases
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15145
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