Metal disordering Cu(II) supramolecular polymers constructed from a tripodal ligand possessing two different functional groups

URN to cite this document:: urn:nbn:de:bvb:355-epub-151485
DOI to cite this document:: 10.5283/epub.15148

Wang, Su-Na ; Bai, Junfeng ; Li, Yizhi ; Scheer, Manfred

; You, Xiaozeng

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Date of publication of this fulltext: 07 Jun 2010 12:51

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Abstract

Two novel coordination polymers with double-layer structures were constructed from a tripodal ligand TCMB (1,3,5-tris(carboxymethoxy) benzene) by controlling the solvent and diffusion velocity of the reaction systems. Both solvated isomers [Cu-3(TCMB)(2)(C5H5N)(3)(H2O)(3) center dot 10H(2)O] (1, P6/m, a = b = 16.753( 1), c = 10.811( 1) angstrom, alpha = beta = 90.00 degrees, gamma = 120.00 ...