Metal disordering Cu(II) supramolecular polymers constructed from a tripodal ligand possessing two different functional groups

URN to cite this document:: urn:nbn:de:bvb:355-epub-151485

Wang, Su-Na ; Bai, Junfeng ; Li, Yizhi ; Scheer, Manfred ; You, Xiaozeng

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Date of publication of this fulltext: 07 Jun 2010 12:51

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Abstract

Two novel coordination polymers with double-layer structures were constructed from a tripodal ligand TCMB (1,3,5-tris(carboxymethoxy)benzene) by controlling the solvent and diffusion velocity of the reaction systems. Both solvated isomers [Cu3(TCMB)2(C5H5N)3(H2O)3·10H2O]( 1, P6/m, a=b= 16.753(1), c= 10.811(1)Å, == 90.00°, = 120.00°) and [Cu3(TCMB)2(C5H5N)3(H2O)3·7.66H2O·DMF]( 2. P-3, a=b= ...