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Terminally Coordinated AsS and PS Ligands

Balázs, Gábor, Green, Jennifer C. and Scheer, Manfred (2006) Terminally Coordinated AsS and PS Ligands. Chemistry - A European Journal 12 (33), pp. 8603-8608.

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The terminal AsS and PS complexes [(N3N)W(ES)] (N3N=N(CH2CH2NSiMe3)3; E=P (3), As (4)) were synthesised by reaction of [(N3N)WAs] and [(N3N)WP], respectively, with cyclohexene sulfide. Both complexes present very short WE and ES bond lengths. The bonding was investigated by density functional theory (DFT) calculations using the fragment calculation method and natural bond orbital (NBO) analysis. ...


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Item type:Article
Date:5 September 2006
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15181
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