Terminally Coordinated AsS and PS Ligands

DOI to cite this document:: 10.5283/epub.15181

Balázs, Gábor ; Green, Jennifer C. ; Scheer, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:54

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Abstract

The terminal AsS and PS complexes [(N3N)W(ES)] (N3N=N(CH2CH2NSiMe3)3; E=P (3), As (4)) were synthesised by reaction of [(N3N)WAs] and [(N3N)WP], respectively, with cyclohexene sulfide. Both complexes present very short WE and ES bond lengths. The bonding was investigated by density functional theory (DFT) calculations using the fragment calculation method and natural bond orbital (NBO) analysis. ...