Terminally Coordinated AsS and PS Ligands

DOI to cite this document:: 10.5283/epub.15181

Balázs, Gábor ; Green, Jennifer C.

; Scheer, Manfred

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Date of publication of this fulltext: 07 Jun 2010 12:54

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Abstract

The terminal AsS and PS complexes [(N3N)W(ES)] (N3N = N(CH2CH2NSiMe3)(3); E=P (3), As (4)) were synthesised by reaction of [(N,N)W As] and [(N3N)W P], respectively, with cyclohexene sulfide. Both complexes present very short W-E and E-S bond lengths. The bonding was investigated by density functional theory (DFT) calculations using the fragment calculation method and natural bond orbital (NBO) ...