Scheer, Manfred, Gregoriades, Laurence John, Virovets, Alexander V., Kunz, Werner, Neueder, Roland and Krossing, Ingo (2006) Reversible Formation of Polymeric Chains by Coordination of Pentaphosphaferrocene with Silver(I) Cations. Angewandte Chemie International Edition 45 (34), pp. 5689-5693.
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Abstract
A fragile coordination polymer: The pentaphosphaferrocene [Cp*Fe(5-P5)] reacts with the AgI salt of the weakly coordinating anion [Al{OC(CF3)3}4]- to yield a polymer comprising cyclo-P5 moieties in an unprecedented 1,2,3-coordination mode (see figure). Analytical data and DFT calculations support the existence of a monomer/dimer/oligomer equilibrium in solution, which is entirely in favor of the monomer at room temperature and shifts to the dimer/oligomer at reduced temperatures.
Export bibliographical data
Item type: | Article | ||||
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Date: | 24 July 2006 | ||||
Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
Identification Number: |
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Keywords: | coordination polymers; density functional calculations; phosphorus; silver; structure elucidation | ||||
Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
Status: | Published | ||||
Refereed: | Unknown | ||||
Created at the University of Regensburg: | Unknown | ||||
Item ID: | 15184 |