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Spherical Cluster Comprising a Four- and Six-Membered-Ring Motif [Ein sphärischer Cluster aus Vier- und Sechsringeinheiten]

DOI to cite this document:
Johnson, Brian P. ; Dielmann, Fabian ; Balázs, Gábor ; Sierka, Marek ; Scheer, Manfred
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Date of publication of this fulltext: 07 Jun 2010 13:01


Magic ball: A spherical aggregate containing a core of 32 inorganic atoms (see structure) was prepared by coordination of a cyclo-P4 tantalum complex to copper(I) chloride. The phosphorus/copper core exhibits an arrangement of alternating four- and six-membered rings, which are reminiscent of the hypothetical Oh-symmetric fullerene C32.

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