Fullerene-Like Nanoballs Formed by Pentaphosphaferrocene and CuBr

DOI to cite this document:: 10.5283/epub.15211

Scheer, Manfred

; Bai, Junfeng ; Johnson, Brian P.

; Merkle, Roger ; Virovets, Alexander

; Anson, Christopher E.

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Date of publication of this fulltext: 07 Jun 2010 13:04

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Abstract

Reaction of [(CpFe)-Fe-x(eta(5)-P-5)] (Cp-x = eta(5)-C5Me5 (1a), eta(5)-C5Me4Et (1b)} with CuBr leads to the fullerene-like nanoballs [((CpFe)-Fe-x (eta(5): eta(1): eta(1): eta(1): eta(1): eta(1)-P-5)}(12) {CuBr)(10 {)Cu2Br3)(5) {Cu-(CH3CN)(2)}(5)} {Cp-x = eta(5)-C5Me5 (5a), eta(5)-C5Me4Et (5b)) comprising a cluster core of 90 non-carbon atoms. In contrast to previous results by variation of ...