One-Dimensional Polymers Based on [{CpMo(CO)2}2(,2-P2)]: Solid-State Conformation Analysis by NMR Spectroscopy and DFT Calculations

DOI to cite this document:: 10.5283/epub.15220

Scheer, Manfred ; Gregoriades, Laurence John ; Bai, Junfeng ; Sierka, Marek ; Brunklaus, Gunther ; Eckert, Hellmut

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Date of publication of this fulltext: 14 Jun 2010 12:06

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Abstract

Reaction of the complex [{CpMo(CO)2}2(,2-P2)] (1) with CuI halides leads to the quantitative formation of the novel one-dimensional linear polymers [CuX{Cp2Mo2(CO)4(,2:1:1-P2)}] (X=Cl (4), Br (5), I (6)). The same products 4 and 5 were obtained when 1 was treated with CuCl2 and CuBr2, respectively. The solid-state structures are compared and their remarkable influence on the respective 31P magic ...