Synthesis and Characterisation of Novel Complexes Containing Group 15 Elements and Their Potential Use as Molecular Precursors for the Formation of Transition Metal Pnictides

Scheer, Manfred ; Vogel, Ulf ; Becker, Uta ; Balzàs, Gàbor ; Scheer, Petra ; Hönle, Wolfgang ; Becker, Michael ; Jansen, Martin

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Date of publication of this fulltext: 14 Jun 2010 12:08

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Details

Item type:	Article
Journal or Publication Title:	European Journal of Inorganic Chemistry
Publisher:	John Wiley & Sons
Volume:	2005
Number of Issue or Book Chapter:	1
Page Range:	pp. 135-141
Date:	18 November 2004
Institutions:	Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:	Value Type 10.1002/ejic.200400640 DOI
Keywords:	Cobalt; Cluster compounds; Phosphorus; Thermochemistry; Tungsten
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Unknown
Created at the University of Regensburg:	Unknown
Item ID:	15226

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Abstract

The reaction of [{W(CO)5}2PCl] with K[Co(CO)4] yields the novel compounds [{W(CO)4Co2(CO)6}{µ3-PW(CO)5}2] (3) and [{(CO)4WCo3(CO)6}{µ3-PW(CO)5}3] (4) along with known derivatives [Co2(CO)6{,2-PW(CO)5}2] (1) and [Co3(CO)9{3-PW(CO)5}] (2). The complex [{W2(CO)8(-CO)}{,2:1:1-PW(CO)5}2)] (5) was synthesised by treating Na2[W2(CO)10] with PBr3. Reaction of K[Mn(CO)5] with SbCl3 affords [Sb{Mn(CO)5}3] ...

Abstract

The reaction of [{W(CO)5}2PCl] with K[Co(CO)4] yields the novel compounds [{W(CO)4Co2(CO)6}{µ3-PW(CO)5}2] (3) and [{(CO)4WCo3(CO)6}{µ3-PW(CO)5}3] (4) along with known derivatives [Co2(CO)6{,2-PW(CO)5}2] (1) and [Co3(CO)9{3-PW(CO)5}] (2). The complex [{W2(CO)8(-CO)}{,2:1:1-PW(CO)5}2)] (5) was synthesised by treating Na2[W2(CO)10] with PBr3. Reaction of K[Mn(CO)5] with SbCl3 affords [Sb{Mn(CO)5}3] (6) in high yields. The spectroscopic and structural characterisation of the novel products is discussed, as well as the thermolytic behaviour of 2, 3 and 6 for the potential formation of novel phases of transition metal pnictides.

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