Synthesis and Characterisation of Novel Complexes Containing Group 15 Elements and Their Potential Use as Molecular Precursors for the Formation of Transition Metal Pnictides

Scheer, Manfred, Vogel, Ulf, Becker, Uta, Balzàs, Gàbor, Scheer, Petra, Hönle, Wolfgang, Becker, Michael and Jansen, Martin (2004) Synthesis and Characterisation of Novel Complexes Containing Group 15 Elements and Their Potential Use as Molecular Precursors for the Formation of Transition Metal Pnictides. European Journal of Inorganic Chemistry 2005 (1), pp. 135-141.

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Abstract

The reaction of [{W(CO)5}2PCl] with K[Co(CO)4] yields the novel compounds [{W(CO)4Co2(CO)6}{µ3-PW(CO)5}2] (3) and [{(CO)4WCo3(CO)6}{µ3-PW(CO)5}3] (4) along with known derivatives [Co2(CO)6{,2-PW(CO)5}2] (1) and [Co3(CO)9{3-PW(CO)5}] (2). The complex [{W2(CO)8(-CO)}{,2:1:1-PW(CO)5}2)] (5) was synthesised by treating Na2[W2(CO)10] with PBr3. Reaction of K[Mn(CO)5] with SbCl3 affords [Sb{Mn(CO)5}3] ...

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