Synthesis and Characterisation of Novel Complexes Containing Group 15 Elements and Their Potential Use as Molecular Precursors for the Formation of Transition Metal Pnictides

DOI to cite this document:: 10.5283/epub.15226

Scheer, Manfred

; Vogel, Ulf ; Becker, Uta ; Balzàs, Gàbor ; Scheer, Petra

; Hönle, Wolfgang ; Becker, Michael ; Jansen, Martin

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Date of publication of this fulltext: 14 Jun 2010 12:08

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Abstract

The reaction of [{W(CO)(5)}(2)PCl] with K[Co(CO)(4)] yields the novel compounds [{W(CO)(4)CO2(CO)(6)}{mu(3)-PW(CO)(5)}(2)] (3) and [{(CO)(4)WCO3(CO)(6)}{mu(3)-PW(CO)(5)}(3)] (4) along with known derivatives [CO2(CO)(6){mu,eta(2)-PW(CO)(5)}(2)] (1) and [CO3(CO)(9){mu(3)-PW(CO)(5)}] (2). The complex [{W-2(CO)(8)(mu-CO)}{mu,eta(2):eta(1):eta(1)-PW(CO)(5)}(2))] (5) was synthesised by treating ...