Go to content
UR Home

Synthesis and Characterisation of Novel Complexes Containing Group 15 Elements and Their Potential Use as Molecular Precursors for the Formation of Transition Metal Pnictides

DOI to cite this document:
Scheer, Manfred ; Vogel, Ulf ; Becker, Uta ; Balzàs, Gàbor ; Scheer, Petra ; Hönle, Wolfgang ; Becker, Michael ; Jansen, Martin
(170kB) - Repository staff only
Date of publication of this fulltext: 14 Jun 2010 12:08


The reaction of [{W(CO)5}2PCl] with K[Co(CO)4] yields the novel compounds [{W(CO)4Co2(CO)6}{µ3-PW(CO)5}2] (3) and [{(CO)4WCo3(CO)6}{µ3-PW(CO)5}3] (4) along with known derivatives [Co2(CO)6{,2-PW(CO)5}2] (1) and [Co3(CO)9{3-PW(CO)5}] (2). The complex [{W2(CO)8(-CO)}{,2:1:1-PW(CO)5}2)] (5) was synthesised by treating Na2[W2(CO)10] with PBr3. Reaction of K[Mn(CO)5] with SbCl3 affords [Sb{Mn(CO)5}3] ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons