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- DOI to cite this document:
- 10.5283/epub.15227
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Abstract
The reaction of [Ru2(CO)3(PBun3)(μ-H)(μ-PBut2)(μ-dppm)] (1a) with tert-butylphosphaethyne leads under hydrodimetalation to the novel phosphaethenyl complex [Ru2(CO)4(μ-PBut2)(μ-dppm){μ-PC(H)But}] (2), which has been characterized by spectroscopic methods as well as by X-ray diffraction. Compound 2 represents the first structurally characterized complex with a phosphaalkenyl ligand of the type μ-PC(H)R bridging two metal centers.
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