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Second Molecular Hyperpolarizability of Mixed Transition Metal, Non-Metal Clusters

Mathur, Pradeep, Chatterjee, Saurav, Singh, Bishnu P., Kundu, Tapan, Trivedi, Rajiv, Umbarkar, Shubhangi B. and Scheer, Manfred (2004) Second Molecular Hyperpolarizability of Mixed Transition Metal, Non-Metal Clusters. Journal of Cluster Science 15 (1), pp. 13-18.

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The real and imaginary parts of third order nonlinear optical susceptibilities (chi (3)) of 10–4M solutions of [{Fe2(CO)6}(mgr 3-Y3P){CpCr(CO)2}] (Y=S (1) or Se (2)) and the well known precursor clusters [Fe3(CO)9(mgr 3-Y)2] (Y=S (3) or Se (4)) in toluene were measured using Z-scan and ARINS techniques respectively. Compounds 1 and 2 possess nearly three times the gamma R values of their ...


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Item type:Article
Date:29 November 2004
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Non-linear; optical; mixed-metal; iron; chromium; carbonyl
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15229
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