Complexes with a Metal-Phosphorus Triple Bond

Johnson, Brian P. ; Balàzs, Gàbor ; Scheer, Manfred

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Date of publication of this fulltext: 14 Jun 2010 12:13

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Abstract

A survey of the existing complexes containing a transition metal-phosphorus triple bond is presented. Based on the different types of these complexes—terminal and asymmetrically bridged complexes with a phosphido ligand as well as the linearly coordinated phosphinidene complexes—their characteristic structural and bonding features as well as trends in their NMR data are discussed and compared. ...