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- DOI to cite this document:
- 10.5283/epub.15234
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Abstract
Mild reduction with metals: Elemental gallium is used as mild reducing agent for transition-metal halides to generate subvalent GaCl ligands in novel clusters. In the reaction of Ga with [{CpRhCl2}] (Cp=5-1,3-C5H3tBu2), clusters with GaCl ligands and with unprecedented two-coordinate Ga centers in a multicenter-multiple-bonding interaction between two rhodium centers are formed (see picture).
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