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First Examples of Electrophilic Addition to a Fe2Q Face of [Fe3(μ3-Q)(CO)9]2− (Q=Se, Te)—Synthesis and Characterisation of [MFe3(μ4-Q)(CO)9Cp*] and [IrFe2(μ3-Q)(CO)7Cp*] (M=Rh, Ir; Cp*=η5-C5(CH3)5)

DOI to cite this document:
10.5283/epub.15235
Konchenko, Sergei N. ; Pushkarevsky, Nikolai A. ; Scheer, Manfred
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Date of publication of this fulltext: 14 Jun 2010 12:13


Abstract

The reaction of [Et4N]2[Fe3(mgr 3-Q)(CO)9] (Q=Se ([Et4N]2[1b]), Te ([Et4N]2[1c])) with [Cp*M(CH3CN)3][CF3SO3]2 (M=Rh, Ir) leads to the addition of a Cp*M2+ unit to a Fe2Q face of the initial cluster. In this way four new heteronuclear clusters [MFe3(mgr 4-Q)(CO)9Cp*] (M=Rh (2b, c); M=Ir (3b, c)) were obtained possessing a butterfly-shaped cluster core bridged by a mgr 4-Q unit. Furthermore, ...

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