Konchenko, Sergei N., Pushkarevsky, Nikolai A. and Scheer, Manfred (2003) First Examples of Electrophilic Addition to a Fe2Q Face of [Fe3(μ3-Q)(CO)9]2− (Q=Se, Te)—Synthesis and Characterisation of [MFe3(μ4-Q)(CO)9Cp*] and [IrFe2(μ3-Q)(CO)7Cp*] (M=Rh, Ir; Cp*=η5-C5(CH3)5). Journal of Cluster Science 14 (3), pp. 299-312.
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Abstract
The reaction of [Et4N]2[Fe3(mgr 3-Q)(CO)9] (Q=Se ([Et4N]2[1b]), Te ([Et4N]2[1c])) with [Cp*M(CH3CN)3][CF3SO3]2 (M=Rh, Ir) leads to the addition of a Cp*M2+ unit to a Fe2Q face of the initial cluster. In this way four new heteronuclear clusters [MFe3(mgr 4-Q)(CO)9Cp*] (M=Rh (2b, c); M=Ir (3b, c)) were obtained possessing a butterfly-shaped cluster core bridged by a mgr 4-Q unit. Furthermore, ...

Export bibliographical data
Item type: | Article | ||||
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Date: | 25 October 2003 | ||||
Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
Identification Number: |
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Keywords: | Cluster; carbonyl complexes; iron; rhodium; iridium; selenium; tellurium | ||||
Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
Status: | Published | ||||
Refereed: | Unknown | ||||
Created at the University of Regensburg: | Unknown | ||||
Item ID: | 15235 |