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Synthesis of Inorganic Fullerene-Like Molecules

Bai, Junfeng, Virovets, Alexander and Scheer, Manfred (2003) Synthesis of Inorganic Fullerene-Like Molecules. Science 300 (5620), pp. 781-783.

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The reaction of [Cp*Fe({eta}5-P5)] with Cu(I)Cl in solvent mixtures of CH2Cl2/CH3CN leads to the formation of entirely inorganic fullerene-like molecules of the formula [{Cp*Fe({eta}5:{eta}1:{eta}1:{eta}1:{eta}1:{eta}1-P5)}12{CuCl}10{Cu2Cl3}5{Cu(CH3CN)2}5] (1) possessing 90 inorganic core atoms. This compound represents a structural motif similar to that of C60: cyclo-P5 rings of ...


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Item type:Article
Date:2 May 2003
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Arsenic; Crystal structure; Gallium; Molybdenum; Phosphorus
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15238
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