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Synthesis of Inorganic Fullerene-Like Molecules

Bai, Junfeng ; Virovets, Alexander ; Scheer, Manfred
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Date of publication of this fulltext: 14 Jun 2010 12:18


Abstract

The reaction of [Cp*Fe({eta}5-P5)] with Cu(I)Cl in solvent mixtures of CH2Cl2/CH3CN leads to the formation of entirely inorganic fullerene-like molecules of the formula [{Cp*Fe({eta}5:{eta}1:{eta}1:{eta}1:{eta}1:{eta}1-P5)}12{CuCl}10{Cu2Cl3}5{Cu(CH3CN)2}5] (1) possessing 90 inorganic core atoms. This compound represents a structural motif similar to that of C60: cyclo-P5 rings of ...

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