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An Unusual Bonding Situation in a Novel AuI-Phosphido Complex with a Planar Au3P3 Framework

Vogel, Ulf ; Sekar, Perumal ; Ahlrichs, Reinhart ; Huniar, Uwe ; Scheer, Manfred
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Date of publication of this fulltext: 14 Jun 2010 12:19


Reaction of the mono-deprotonated derivative of [{Cp(CO)2Mo}2(-PH2)(-H)] (1) leads to the novel complex [{Cp(CO)2Mo}2(-H){3-P(H)Au(PPh3)}] (2). In contrast the reaction of the analogous Cr derivative [{Cp(CO)2Cr}2(-PH2)(-H)] (1a) leads under identical conditions to a planar Au3P3 cluster [{CpCr(CO)2}6(P3Au3)] (3). Both complexes were completely structurally and spectroscopically characterised. ...


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