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The Stabilisation of Monomeric Parent Compounds of Phosphanyl- and Arsanylboranes

Vogel, Ulf, Hoemensch, Petra, Schwan, Karl-Christian, Timoshkin, Alexey Y. and Scheer, Manfred (2003) The Stabilisation of Monomeric Parent Compounds of Phosphanyl- and Arsanylboranes. Chemistry - A European Journal 9 (2), pp. 515-519.

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The structures of the parent compounds of phosphanyl- and arsanylboranes, H2BPH2 and H2BAsH2, were calculated by DFT-B3LYP methods. Such compounds have not previously been obtained preparatively. By applying the concept of Lewis acid/base stabilisation, [(CO)5W(H2EBH2NMe3)] (E=P (3), As (4)) derivatives have been synthesised by the metathesis reactions between Li[(CO)5WEH2] and ClH2BNMe3 (E=P, ...


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Item type:Article
Date:16 January 2003
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:arsenic; boron; density functional calculations; phosphorus; tungsten
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15241
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