A Synthetic Approach to Novel Group 13/15 Element Complexes

DOI to cite this document:: 10.5283/epub.15242

Leiner, Eva ; Scheer, Manfred

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Date of publication of this fulltext: 14 Jun 2010 12:20

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Abstract

The gallium chloro complex [GaCl{Fe(CO)2Cp}2] (Cp = η5-C5H5) was reacted with KP(SiMe3)2 under special conditions to yield the complexes [{CpFe(CO)}2{μ-(CO)}[μ-Ga{CpFe(CO)2}]] (1) and [{CpFe(CO)2}GaP(SiMe3)]4 (2). Furthermore, [[{CpFe(CO)2}ClGa](μ-PPh2)2FeCpCO] (4) was obtained by the reaction of [GaCl{Fe(CO)2Cp}2] with LiPPh2. Complexes 1, 2, and 4 have been characterized spectroscopically and ...