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- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.15243
Zusammenfassung
The reaction between the cluster dianion [Fe3(μ3-Y)(CO)9]2− (1) (Y=Se (a), Te (b)) and MesSbBr2 leads to the formation of [Fe3(μ3-Y)(μ3-SbMes)(CO)9] (2a,b) (Mes=2,4,6-Me3C6H2). The molecular structures of both compounds were established by single crystal X-ray diffraction and reveals nido cluster cores containing square pyramidal FeSbFeY units capped by a third Fe carbonyl fragment as an apical ...
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