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Pentaphosphaferrocene as a Linking Unit for the Formation of One- and Two-Dimensional Polymers [Pentaphosphaferrocen als verknüpfende Einheit in ein- und zweidimensionalen Polymeren]

Bai, Junfeng ; Virovets, Alexander V. ; Scheer, Manfred
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Date of publication of this fulltext: 14 Jun 2010 12:21


Different copper halide, different copper product: The cyclo-P5-ligand complex [Cp*Fe(5-P5)] (1; Cp*=C5Me5) reacts with CuBr and CuI to give two-dimensional networks in which 1 is the linking unit. However, a novel one-dimensional-chain coordination polymer (see picture) is formed with CuCl.

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