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Synthesis and Structure of Novel Complexes of Gallium

Leiner, Eva, Hampe, Oliver and Scheer, Manfred (2002) Synthesis and Structure of Novel Complexes of Gallium. European Journal of Inorganic Chemistry 2002 (3), pp. 584-590.

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[Cp*GaCl2] (Cp* = 1-C5Me5) reacts with K[Co(CO)4] with elimination of KCp* and KCl to form the novel ionic complexes [K(toluene)2][Ga{Co2(CO)6(-CO)}2] (1) and K[GaCl{Co2(CO)6(-CO)}{Co(CO)4}] (2), where the gallium atoms possess the coordination number four. The reaction of [{Co(CO)4}2GaCl(THF)] with LiCp* leads to the ionic product [Li(THF)][Ga{Co2(CO)6(-CO)}2] (3). The [Ga{Co2(CO)6(-CO)}2]- ...


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Item type:Article
Date:29 January 2002
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Metathesis; Iron; Gallium; Cobalt; Cyclopentadienyl ligands
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15250
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