Cp*GaCl2 and Cp*2GaCl (Cp*=η1-C5Me5) as starting materials for novel Group 13 element complexes - University of Regensburg Publication Server

DOI to cite this document:: 10.5283/epub.15251

Leiner, Eva ; Scheer, Manfred

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Date of publication of this fulltext: 14 Jun 2010 12:23

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Abstract

Reactions of Cp*GaCl2 and Cp*2GaCl (Cp*=η1-C5Me5), respectively, with different carbonylmetalate anions are compared to yield the transition-metal–gallium complexes [(η5-Cp*Ga)W(CO)5] (1), [Fe2(CO)6{μ-(η5-Cp*Ga)}2{μ-(η3-Cp*Ga)}] (2), [Ga{Mn(CO)5}3] (3), [Cp*2Ga{Mn(CO)5}] (4), [Co2(CO)6{μ-(η5-Cp*Ga)}2Co(CO)3] (5) and [{(η5-Cp)Fe(CO)}2(μ-CO){μ2-(η5-Cp*Ga}] (6). The results show that both starting ...