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Complexes with a Metal-Phosphorus Triple Bond as Versatile Building Blocks in Coordination and Organometallic Chemistry

Scheer, Manfred ; Schiffer, Michael ; Leiner, Eva ; Johnson, Brian P. ; Haindl, Corinna ; Umbarkar, Shubhangi


Trapping reactions of the phosphido complex intermediate [Cp*(CO) 2 W ıP →W(CO) 5 ], generated by thermolysis of [Cp*PlcubW(CO) 5 rcub 2 ] 1 , occur via [2 + 2] cycloaddition reactions with P 4 , phosphaalkynes, alkynes, and [CpMo(CO) 2 ] 2 , respectively. However, with nitriles, insertion reactions into the P--C σbond of 1 are observed already at room temperature to give novel P-containing ...


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