Vogel, Ulf, Timoshkin, Alexey Y. and Scheer, Manfred (2001) Lewis Acid/Base Stabilized Phosphanylalane and -gallane [Lewis-Säure/Base-stabilisiertes Phosphanylalan und -gallan]. Angewandte Chemie International Edition 40 (23), pp. 4409-4412.
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Abstract
Neither synthesis nor detection in matrix isolation experiments has been accomplished for the parent compounds of phosphanylalanes and -gallanes of type A. H2 elimination reactions between [(CO)5WPH3] and H3ENMe3 (E=Al, Ga) have enabled the first synthesis of Lewis acid/base stabilized complexes of the type B. Comprehensive density functional theory (DFT) calculations on the aluminum systems verify the high stability of the complexes of type B.
Export bibliographical data
Item type: | Article | ||||
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Date: | 28 November 2001 | ||||
Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
Identification Number: |
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Keywords: | aluminum; density functional calculations; gallium; Lewis acids; phosphorus | ||||
Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
Status: | Published | ||||
Refereed: | Unknown | ||||
Created at the University of Regensburg: | Unknown | ||||
Item ID: | 15333 |