Go to content
UR Home

Lewis Acid/Base Stabilized Phosphanylalane and -gallane [Lewis-Säure/Base-stabilisiertes Phosphanylalan und -gallan]

Vogel, Ulf, Timoshkin, Alexey Y. and Scheer, Manfred (2001) Lewis Acid/Base Stabilized Phosphanylalane and -gallane [Lewis-Säure/Base-stabilisiertes Phosphanylalan und -gallan]. Angewandte Chemie International Edition 40 (23), pp. 4409-4412.

[img]PDF
Download (107kB) - Repository staff only
Date of publication of this fulltext: 14 Jun 2010 12:37

at publisher (via DOI)


Abstract

Neither synthesis nor detection in matrix isolation experiments has been accomplished for the parent compounds of phosphanylalanes and -gallanes of type A. H2 elimination reactions between [(CO)5WPH3] and H3ENMe3 (E=Al, Ga) have enabled the first synthesis of Lewis acid/base stabilized complexes of the type B. Comprehensive density functional theory (DFT) calculations on the aluminum systems verify the high stability of the complexes of type B.


Export bibliographical data



Item type:Article
Date:28 November 2001
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/1521-3773(20011203)40:23<4409::AID-ANIE4409>3.0.CO;2-FDOI
Keywords:aluminum; density functional calculations; gallium; Lewis acids; phosphorus
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:15333
Owner only: item control page

Downloads

Downloads per month over past year

  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons