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- DOI to cite this document:
- 10.5283/epub.15337
Abstract
Oxidative Addition Reactions of Complexed Phosphine and Arsine at Platinum(0) Complexes The reactions of E(SiMe3)3 with [W(CO)5thf] yield after alcoholysis in a one-pot reaction the complexes [(CO)5WEH3] (1) (E = P(a), As(b)). This procedure circumvents the direct use of gaseous phosphine and arsine, respectively. Complexes 1 react with [(C2H4)Pt(PPh3)2] in an oxidative addition type reaction to ...
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