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Zur oxidativen Addition von komplexierten Phosphanen bzw. Arsanen an Platin(0)-Komplexen

Vogel, Ulf ; Scheer, Manfred
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Date of publication of this fulltext: 14 Jun 2010 12:39


Abstract

Oxidative Addition Reactions of Complexed Phosphine and Arsine at Platinum(0) Complexes The reactions of E(SiMe3)3 with [W(CO)5thf] yield after alcoholysis in a one-pot reaction the complexes [(CO)5WEH3] (1) (E = P(a), As(b)). This procedure circumvents the direct use of gaseous phosphine and arsine, respectively. Complexes 1 react with [(C2H4)Pt(PPh3)2] in an oxidative addition type reaction to ...

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