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Reactivity Study of the P2 Ligand Complex [lcubCpCr(CO)2rcub2(μ,η2-P2)]

Umbarkar, Shubhangi B., Sekar, Perumal and Scheer, Manfred (2001) Reactivity Study of the P2 Ligand Complex [lcubCpCr(CO)2rcub2(μ,η2-P2)]. Phosphorous and Sulfur and the Related Elements 169 (1), pp. 205-208.

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The complex [lcubCpCr(CO)2rcub2(μ-η2-P2)] has shown highly contrasting reactivity behavior towards ECl3 (E = P, As, Sb) and LiBEt3H. The reaction with ECl3 has yielded the first example of cyclo-P2E ligand complexes, [Cp(CO)2Cr(η3-P2E)]. On the other hand, the reaction with LiBEt3H led to P-P bond cleavage and formation of novel PH2 containing complexes [Cp2(CO)4Cr2(μ-PH2)(μ-H)], and ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:phosphorous; chromium; gold; cluster; cyclopentadiene
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15342
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