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Reactivity Study of the P2 Ligand Complex [lcubCpCr(CO)2rcub2(μ,η2-P2)]

Umbarkar, Shubhangi B. ; Sekar, Perumal ; Scheer, Manfred


The complex [lcubCpCr(CO)2rcub2(μ-η2-P2)] has shown highly contrasting reactivity behavior towards ECl3 (E = P, As, Sb) and LiBEt3H. The reaction with ECl3 has yielded the first example of cyclo-P2E ligand complexes, [Cp(CO)2Cr(η3-P2E)]. On the other hand, the reaction with LiBEt3H led to P-P bond cleavage and formation of novel PH2 containing complexes [Cp2(CO)4Cr2(μ-PH2)(μ-H)], and ...


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