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Complexes with a Metal Phosphorus Triple Bond - a Novel Class of Highly Reactive Compounds

Umbarkar, Shubhangi B. ; Sekar, Perumal ; Scheer, Manfred


A novel approach to highly reactive phosphido complex intermediates of the type [LnM=P→M'(CO)5] (M' = Cr, W) is achieved via the Cp* migration from a σ-bound situation at a P atom in a phosphinidene complex [Cp*PlcubW(CO)5rcub2] to the η5-coordination at the transition metal. Consequently those compounds show a high “side-on” reactivity. Their reaction behavior with phosphaalkynes, alkynes and ...


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