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Abbaureaktionen an 3-(2'-(2"Dimethylaminoäthyl)-phenyl)iso-chromanen

URN to cite this document:
urn:nbn:de:bvb:355-epub-154503
DOI to cite this document:
10.5283/epub.15450
Wiegrebe, Wolfgang ; Stephan, H. M. ; Fricke, J. ; Schlunegger, U. P.
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Date of publication of this fulltext: 22 Jun 2010 06:22


Abstract

Summary:
Degradation of the /?-dimethylaminoethyl sidechain of properly substituted 3-aryl-isochromanes
produce inter alia the amines 2, the styrenes 3, the aldehyde 5b and the carboxylic acid 4b.
The racemates of the amine 15 and the aldehyd 5b were resolved; the chiral center of the
menthoxycarbonyl-hydrazone was eliminated b y ester interchange.


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