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Synthesis and Properties of Novel Metal-Linked Pn Ligand Complexes

Sekar, Perumal ; Umbarkar, Shubhangi B. ; Scheer, Manfred ; Voigt, Andreas ; Kirmse, Reinhard
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Date of publication of this fulltext: 21 Jun 2010 12:19


Abstract

The reaction of [CpCr(CO)3]2 with P4 in toluene at 90 °C for 5 h affords the triple-decker sandwich complex [CpCr(CO)(3-P3)(CpCr)2(,1:5:5-P5)] (1) as a new product, along with the previously described products with P2, P3, and P10 units. The structure of the paramagnetic complex 1 has been established by single-crystal X-ray diffraction methods. A novel complex ...

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