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On the pathway of the 1–5 migration of a Cp* ligand

URN to cite this document:
Schiffer, Michael ; Scheer, Manfred
Date of publication of this fulltext: 21 Jun 2010 12:35


The thermolysis and photolysis, respectively, of the phosphinidene complex [Cp*P{W(CO)5}2] 1 in the presence of MeCCMe leads to the three-membered heterocycle [(2-CH2C5Me4)W(CO)4C{(CH3)CH(CH3)}PW(CO)5] 4 with an unusual 2-coordinated CH2C5Me4 ligand formed by a 1,4-sigmatropic hydrogen shift; the crystal structure and the spectroscopic data of 4 are discussed.

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