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Pnictides as Symmetrically Bridging Ligands in Novel Neutral Complexes

Scheer, Manfred, Müller, Jan, Schiffer, Michael, Baum, Gerhard and Winter, Rainer F. (2000) Pnictides as Symmetrically Bridging Ligands in Novel Neutral Complexes. Chemistry - A European Journal 6 (7), pp. 1252-1257.

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The reaction of [LWCl] (3) [L=N(CH2CH2NiPr)3] with LiE/SiMe3)2 (E=P, As, Sb) yields the novel, neutral pnictido-bridged complexes [LW=E=WL] (5-7). By following the reaction, which starts from the LiP/SiMe3)2 derivative, by 31P NMR spectroscopy, the formation of an intermediate with a terminal pnictido ligand can be ruled out. The paramagnetic complexes 5-7 are comprehensively spectroscopically ...


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Item type:Article
Date:3 April 2000
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:antimony; heterocumulenes; pnictides; tripodal ligands; tungsten
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15467
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