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Pnictides as Symmetrically Bridging Ligands in Novel Neutral Complexes

Scheer, Manfred ; Müller, Jan ; Schiffer, Michael ; Baum, Gerhard ; Winter, Rainer F.
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Date of publication of this fulltext: 21 Jun 2010 12:35


Abstract

The reaction of [LWCl] (3) [L=N(CH2CH2NiPr)3] with LiE/SiMe3)2 (E=P, As, Sb) yields the novel, neutral pnictido-bridged complexes [LW=E=WL] (5-7). By following the reaction, which starts from the LiP/SiMe3)2 derivative, by 31P NMR spectroscopy, the formation of an intermediate with a terminal pnictido ligand can be ruled out. The paramagnetic complexes 5-7 are comprehensively spectroscopically ...

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