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Naked Phosphorus as a Bent Bridging Ligand [Nackter Phosphor als gewinkelt verbrückender Ligand]

Kramkowski, Peter and Scheer, Manfred (2000) Naked Phosphorus as a Bent Bridging Ligand [Nackter Phosphor als gewinkelt verbrückender Ligand]. Angewandte Chemie International Edition 39 (5), pp. 928-931.

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Abstract

The metathesis reaction of [W2(OAr)6] (Ar=2,6-Me2C6H3) with tBuCP leads to the formation of a complex containing the first bent bridging P1 ligand with the coordination number 2 (see structure, atom P2). This mode of coordination was previously exclusively found for nitrogen and was unknown for the heavier homologues. The lone pair of electrons of the phosphorus ligand coordinates Lewis acidic M(CO)5 fragments (M=Cr, W).


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Item type:Article
Date:3 March 2000
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/(SICI)1521-3773(20000303)39:5<928::AID-ANIE928>3.0.CO;2-ADOI
Keywords:metathesis; multiple bonds; P ligands; tungsten
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:15470
Owner only: item control page

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