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Transition Metal Induced Pentamerization of a Phosphaalkyne [Übergangsmetallinduzierte Pentamerisierung eines Phosphaalkins]

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Kramkowski, Peter ; Scheer, Manfred
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Date of publication of this fulltext: 21 Jun 2010 12:39


The metalla-norbornadiene complex 1, extended by two phosphaalkyne units in the 1,4-position, is formed by an unprecedented pentamerization of the phosphaalkyne MesCP (Mes=2,4,6-Me3C6H2) in the coordination sphere of the transition metal complex [W(CO)5(thf)].

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