Transition Metal Induced Pentamerization of a Phosphaalkyne [Übergangsmetallinduzierte Pentamerisierung eines Phosphaalkins]

DOI to cite this document:: 10.5283/epub.15474

Kramkowski, Peter ; Scheer, Manfred

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Date of publication of this fulltext: 21 Jun 2010 12:39

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Item type:	Article
Journal or Publication Title:	Angewandte Chemie International Edition
Publisher:	John Wiley & Sons
Volume:	31
Number of Issue or Book Chapter:	21
Page Range:	pp. 3183-3186
Date:	26 October 2000
Institutions:	Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:	Carbonyl complexes; Phosphaalkynes; Tungsten
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Unknown
Created at the University of Regensburg:	Unknown
Item ID:	15474

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Abstract

The metalla-norbornadiene complex 1, extended by two phosphaalkyne units in the 1,4-position, is formed by an unprecedented pentamerization of the phosphaalkyne MesCP (Mes=2,4,6-Me3C6H2) in the coordination sphere of the transition metal complex [W(CO)5(thf)].

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