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Complexes with a Monohapto Bound Phosphorus Tetrahedron and Phosphaalkyne

Gröer, Thomas, Baum, Gerhard and Scheer, Manfred (1998) Complexes with a Monohapto Bound Phosphorus Tetrahedron and Phosphaalkyne. Organometallics 17 (26), pp. 5916-5919.

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The reaction of white phosphorus with the coordinatively unsaturated [M(CO)3(PR3)2] complexes (M = Mo, W; R = Cy, Pri) yields the compounds [M(CO)3(PR3)2(η1-P4)] in which the P4-tetrahedron is end-on bonded to the metal. In the same manner reacts Ar‘CP (Ar‘ = C6H2But3-2,4,6) with this complex to give [W(CO)3(PCy3)2(η1-PCAr‘)]. The X-ray structures of the products are discussed, and for the ...


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Item type:Article
Date:20 November 1998
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15478
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