A study of the photochemical reaction between W2(OCH2tBu)6 and P4. Characterization of the phosphido cluster W4(P)2(OCH2tBu)10

DOI to cite this document:: 10.5283/epub.15481

Chisholm, Malcolm H. ; Folting, Kristen ; Scheer, Manfred

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Date of publication of this fulltext: 21 Jun 2010 12:43

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Abstract

The photochemical reaction between W2(OCH2tBu)6 and P4 has been studied by NMR spectroscopy in toluene-d8 and those reactions have been complemented by studies on the bench top. A complex sequence of reactions is implicated by the formation of a variety of products, one of which has been observed previously in the thermal reaction between W2(OCH2tBu)6L2 where L = py and HNMe2 and P4, namely ...