Go to content
UR Home

A Novel Synthetic Approach to Highly Reactive Intermediates Containing a Metal-Phosphorus Triple Bond

DOI to cite this document:
10.5283/epub.15482
Scheer, Manfred ; Leiner, Eva ; Kramkowski, Peter ; Schiffer, Michael ; Baum, Gerhard
[img]PDF
(246kB) - Repository staff only
Date of publication of this fulltext: 21 Jun 2010 12:42


Abstract

A new synthetic route providing access to the highly reactive intermediate [Cp*(CO)2WPW(CO)5] with a tungsten-phosphorus triple bond is presented (see scheme). The intermediate is formed by thermolysis of [Cp*P{W(CO)5}2] by Cp* migration from the phosphorus to give 5 coordination at the transition metal. Addition of other reactive molecules to solutions conatining the intermediate provides a simple approach to novel W/P-containing ligands.


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: daten@ur.de
0941 943 -5707

Contact persons