Scheer, Manfred, Leiner, Eva, Kramkowski, Peter, Schiffer, Michael and Baum, Gerhard (1998) A Novel Synthetic Approach to Highly Reactive Intermediates Containing a Metal-Phosphorus Triple Bond. Chemistry - A European Journal 4 (10), pp. 1917-1923.
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Abstract
A new synthetic route providing access to the highly reactive intermediate [Cp*(CO)2WPW(CO)5] with a tungsten-phosphorus triple bond is presented (see scheme). The intermediate is formed by thermolysis of [Cp*P{W(CO)5}2] by Cp* migration from the phosphorus to give 5 coordination at the transition metal. Addition of other reactive molecules to solutions conatining the intermediate provides a simple approach to novel W/P-containing ligands.
Export bibliographical data
Item type: | Article | ||||
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Date: | 14 December 1998 | ||||
Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
Identification Number: |
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Keywords: | C-H activation; Cyclopentadienes; Intermediates; P ligands; Tungsten | ||||
Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
Status: | Published | ||||
Refereed: | Unknown | ||||
Created at the University of Regensburg: | Unknown | ||||
Item ID: | 15482 |