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Reaction behaviour of a complex containing a tungsten phosphorus triple bond with -acceptor compounds of group 13

URN to cite this document:
urn:nbn:de:bvb:355-epub-154835
DOI to cite this document:
10.5283/epub.15483
Scheer, Manfred ; Müller, Jan ; Baum, Gerhard ; Häser, Marco
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Date of publication of this fulltext: 21 Jun 2010 12:44


Abstract

[LWPGaCl3] 5 [L = N(CH2CH2NSiMe3)3] is prepared by treatment of [LWP] with (GaCl3)2; decomposition of 5 in CH2Cl2 affords dimerisation under Me3SiCl elimination to give a cationic W2P2 tetrahedral complex 6; both complexes are structurally characterised.


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