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Reaction behaviour of a complex containing a tungsten phosphorus triple bond with -acceptor compounds of group 13

URN to cite this document:
Scheer, Manfred ; Müller, Jan ; Baum, Gerhard ; Häser, Marco
Date of publication of this fulltext: 21 Jun 2010 12:44


[LWPGaCl3] 5 [L = N(CH2CH2NSiMe3)3] is prepared by treatment of [LWP] with (GaCl3)2; decomposition of 5 in CH2Cl2 affords dimerisation under Me3SiCl elimination to give a cationic W2P2 tetrahedral complex 6; both complexes are structurally characterised.

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